A multistep continuous flow synthesis machine for the preparation of pyrazoles via a metal-free amine-redox process† †Raw spectra can be found at https://www.repository.cam.ac.uk/handle/1810/252343. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c5re00082c Click here for additional data file. Click here for additional data file.

A multicomponent approach for the preparation of homoallylic alcohols† †Raw spectra can be found at DOI: 10.17863/CAM.591 ‡ ‡Electronic supplementary information (ESI) available. CCDC 1483699. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02581a Click here for additional data file. Click here for additional data file.

Crystallization-induced dual emission from metal- and heavy atom-free aromatic acids and esters† †Electronic supplementary information (ESI) available. CCDC 1044990 and 1044991. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00253b Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file.

Redox-promoted associative assembly of metal–organic materials† †Electronic supplementary information (ESI) available: Experimental procedures, compound characterization data, and X-ray crystallographic data for compounds 3–7 and 9–11. CCDC 1405641–1405645, 1429643, 1405647 and 1405648. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02214b Click here for additional data file. Click here for additional data file.

We develop an associative synthesis of metal–organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal–...

Solid state organic amine detection in a photochromic porous metal organic framework† †Electronic supplementary information (ESI) available: Experimental procedures and additional supporting data. CCDC 1024270 and 1024271. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03224a Click here for additional data file. Click here for additional data file.

Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details, spectral data, and crystallographic results. CCDC 1533276 and 1533274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01703k Click here for additional data file. Click here for additional data file.